Resource data
Practical Synthesis of Dirhodium (II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]
TSUTSUI, Hideyuki
ABE, Takumi
NAKAMURA, Seiichi
ANADA, Masahiro
HASHIMOTO, Shunichi
Location:
http://hdl.handle.net/2115/26434
Chemical & pharmaceutical bulletin. 53(10), 2005, 1366-1368
An efficient and reliable procedure for the preparation of dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leuci-nate], Rh_2(S-PTTL)_4, a universally effective catalyst for a range of enantioselective carbene transformations, is described. The N-phthaloylation of (S)-tert-leucine by the method of Bose with essentially no racemization is a key to this process.
Belongs to: Hokkaido University Collection of Scholarly and Academic Papers
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Detalles del recurso
|
Practical Synthesis of Dirhodium (II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]
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| Id. |
26873104 |
| Idioma |
inglés
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| Titulo |
Practical Synthesis of Dirhodium (II) Tetrakis[N-phthaloyl-(S)-tert-leucinate] |
| Autor(es) |
TSUTSUI, Hideyuki
ABE, Takumi
NAKAMURA, Seiichi
ANADA, Masahiro
HASHIMOTO, Shunichi
|
| Location |
http://hdl.handle.net/2115/26434
Chemical & pharmaceutical bulletin. 53(10), 2005, 1366-1368
|
| Versión |
1.0 |
| Estado |
Final
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| Descripción |
An efficient and reliable procedure for the preparation of dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leuci-nate], Rh_2(S-PTTL)_4, a universally effective catalyst for a range of enantioselective carbene transformations, is described. The N-phthaloylation of (S)-tert-leucine by the method of Bose with essentially no racemization is a key to this process.
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| Palabras clave |
tert-leucine
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| Tipo de recurso |
article
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| Tipo de Interactividad |
Expositivo
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| Nivel de Interactividad |
muy bajo
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| Audiencia |
Estudiante
Profesor
Autor
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| Estructura |
Atomic |
| Coste |
no
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| Copyright |
sí
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| Requerimientos técnicos |
Browser: Any
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| Fecha de contribución |
26-oct-2007 |
| Contacto |
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