Resource data
Selective trifluorination of alkyl aryl sulfides using IF5
Ayuba, Shinichi
Hiramatsu, Chiharu
Fukuhara, Tsuyoshi
Hara, Shoji
?, ??
Location:
http://www.elsevier.com/wps/find/journaldescription.cws_home/942/description#description
http://hdl.handle.net/2115/560
Tetrahedron. 60(50), 2004, 11445-11541
http://dx.doi.org/10.1016/j.tet.2004.09.076
In the reaction of IF5 with alkyl aryl sulfides in heptane under reflux conditions, the arylthio group migrated once and three fluorine atoms were selectively introduced on the alkyl chain. In order to find the reason why the reaction stopped at the trifluorination step, we examined the oxidation potentials of the starting material, a reaction intermediate, and the product, and the time course of the reactions.
Belongs to: Hokkaido University Collection of Scholarly and Academic Papers
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Detalles del recurso
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Selective trifluorination of alkyl aryl sulfides using IF5
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| Id. |
5707262 |
| Idioma |
inglés
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| Titulo |
Selective trifluorination of alkyl aryl sulfides using IF5 |
| Autor(es) |
Ayuba, Shinichi
Hiramatsu, Chiharu
Fukuhara, Tsuyoshi
Hara, Shoji
?, ??
|
| Location |
http://www.elsevier.com/wps/find/journaldescription.cws_home/942/description#description
http://hdl.handle.net/2115/560
Tetrahedron. 60(50), 2004, 11445-11541
http://dx.doi.org/10.1016/j.tet.2004.09.076
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| Versión |
1.0 |
| Estado |
Final
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| Descripción |
In the reaction of IF5 with alkyl aryl sulfides in heptane under reflux conditions, the arylthio group migrated once and three fluorine atoms were selectively introduced on the alkyl chain. In order to find the reason why the reaction stopped at the trifluorination step, we examined the oxidation potentials of the starting material, a reaction intermediate, and the product, and the time course of the reactions.
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| Tipo |
84063 bytes
application/pdf
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| Palabras clave |
Halogenation
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| Tipo de recurso |
article (author version)
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| Tipo de Interactividad |
Expositivo
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| Nivel de Interactividad |
muy bajo
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| Audiencia |
Estudiante
Profesor
Autor
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| Estructura |
Atomic |
| Coste |
no
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| Copyright |
sí
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| Formatos |
84063 bytes
application/pdf
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| Requerimientos técnicos |
Browser: Any
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| Fecha de contribución |
25-oct-2007 |
| Contacto |
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