The emission spectra of H2+CH4 plasmas excited at 50 Hz–13.56 MHz were measured. The emission intensity ratios of H?/H*2 (3?g?3?u) from H2+CH4 plasma at 50 Hz and 13.56 MHz were about 0.7 and 0.05, respectively. The electron temperature was obtained from the two-line radiance ratio method using the Balmer lines (H? and H?), and rapidly decreased with an increase above 200 kHz. The electron temperature for H2+CH4 plasma is 16 000 K at 1 kHz and 8200 K at 13.56 MHz. The plasma-maintaining voltages for H2 and H2+CH4 mixtures were also measured. The maintaining voltages were constant below 200 kHz, and rapidly decreased between 200 kHz and 13.56 MHz. The position dependence of emission intensity was also measured for H?, H?, and H*2 at 50 Hz and 13.56 MHz. The results are interpreted in terms of the electron distribution in the plasma.