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Gel friction: A model based on surface repulsion and adsorption
Gong, Jianping
Osada, Yoshihito
??, ??
Location: http://hdl.handle.net/2115/5721
The Journal of Chemical Physics. 109(18), 1998, 8062-8068
http://dx.doi.org/10.1063/1.477453

A model describing the frictional force produced when a polymer gel is sliding on a solid surface has been proposed from the viewpoint of solvated polymer repulsion and adsorption theory at a solid surface. General relations for the frictional force f expressed as functions of the normal loading P, sliding velocity v, the polymer volume fraction ?, or the elastic modulus E of the gel, etc., have been derived by applying scaling relations to the model. For the repulsive case, f is ascribed to the viscous flow of solvent at the interface and f is theoretically demonstrated to be proportional to the sliding velocity v and the normal pressure P when the pressure is smaller than the elastic modulus of the gel. For the attractive case, in addition to the hydrodynamic friction, the force to detach the adsorbing chain from the substrate appears as friction. When v is not very large, f ? v. At an intermediate velocity, f has a velocity dependence less than linear, depending on the strength of adsorption. At a higher sliding velocity, f ? v again since the hydrodynamic friction becomes predominant at this stage. The theoretical results coincide well with some experimental observations that confirm the essential feature of the model.

Belongs to: Hokkaido University Collection of Scholarly and Academic Papers

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Gel friction: A model based on surface repulsion and adsorption
Id. 5709664
Idioma inglés
Titulo Gel friction: A model based on surface repulsion and adsorption
Autor(es) Gong, Jianping
Osada, Yoshihito
??, ??
Location http://hdl.handle.net/2115/5721
The Journal of Chemical Physics. 109(18), 1998, 8062-8068
http://dx.doi.org/10.1063/1.477453
Versión 1.0
Estado Final
Descripción A model describing the frictional force produced when a polymer gel is sliding on a solid surface has been proposed from the viewpoint of solvated polymer repulsion and adsorption theory at a solid surface. General relations for the frictional force f expressed as functions of the normal loading P, sliding velocity v, the polymer volume fraction ?, or the elastic modulus E of the gel, etc., have been derived by applying scaling relations to the model. For the repulsive case, f is ascribed to the viscous flow of solvent at the interface and f is theoretically demonstrated to be proportional to the sliding velocity v and the normal pressure P when the pressure is smaller than the elastic modulus of the gel. For the attractive case, in addition to the hydrodynamic friction, the force to detach the adsorbing chain from the substrate appears as friction. When v is not very large, f ? v. At an intermediate velocity, f has a velocity dependence less than linear, depending on the strength of adsorption. At a higher sliding velocity, f ? v again since the hydrodynamic friction becomes predominant at this stage. The theoretical results coincide well with some experimental observations that confirm the essential feature of the model.
Tipo 157305 bytes
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Palabras clave 431
Tipo de recurso article
Tipo de Interactividad Expositivo
Nivel de Interactividad muy bajo
Audiencia Estudiante
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Estructura Atomic
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Copyright
Copyright © 1998 American Institute of Physics
Formatos 157305 bytes
application/pdf
Requerimientos técnicos Browser: Any
Relación [References] http://www.aip.org/
Fecha de contribución 25-oct-2007
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