Resource data
Synthesis of ?-Boryl-?,?-unsaturated Carbonyl Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates
Takagi, Jun
Kamon, Akihiro
Ishiyama, Tatsuo
Miyaura, Norio
Location:
http://hdl.handle.net/2115/14605
Synlett. 2002(11), 2002, 1880-1882
http://dx.doi.org/10.1055/s-2002-34869
Cross-coupling reaction of bis(pinacolato)diboron with ?-(trifluoromethanesulfonyloxy)-?,?-unsaturated carbonyl compounds was carried out in the presence of PdCl2(PPh3)2-2PPh3 (3 mol%) and KOPh in toluene or K2CO3 in dioxane for the synthesis of cyclic and acyclic ?-boryl-?,?-unsaturated esters, amides, and ketones in high yields.
Belongs to: Hokkaido University Collection of Scholarly and Academic Papers
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Detalles del recurso
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Synthesis of ?-Boryl-?,?-unsaturated Carbonyl Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates
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| Id. |
7578843 |
| Idioma |
inglés
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| Titulo |
Synthesis of ?-Boryl-?,?-unsaturated Carbonyl Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates |
| Autor(es) |
Takagi, Jun
Kamon, Akihiro
Ishiyama, Tatsuo
Miyaura, Norio
|
| Location |
http://hdl.handle.net/2115/14605
Synlett. 2002(11), 2002, 1880-1882
http://dx.doi.org/10.1055/s-2002-34869
|
| Versión |
1.0 |
| Estado |
Final
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| Descripción |
Cross-coupling reaction of bis(pinacolato)diboron with ?-(trifluoromethanesulfonyloxy)-?,?-unsaturated carbonyl compounds was carried out in the presence of PdCl2(PPh3)2-2PPh3 (3 mol%) and KOPh in toluene or K2CO3 in dioxane for the synthesis of cyclic and acyclic ?-boryl-?,?-unsaturated esters, amides, and ketones in high yields.
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| Tipo |
212791 bytes
application/pdf
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| Palabras clave |
diboron
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| Tipo de recurso |
article (author version)
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| Tipo de Interactividad |
Expositivo
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| Nivel de Interactividad |
muy bajo
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| Audiencia |
Estudiante
Profesor
Autor
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| Estructura |
Atomic |
| Coste |
no
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| Copyright |
sí
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| Formatos |
212791 bytes
application/pdf
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| Requerimientos técnicos |
Browser: Any
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| Fecha de contribución |
25-oct-2007 |
| Contacto |
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