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Detalles del recurso
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Inter- and Intramolecular Additions of 1-Alkenylboronic Acids or Esters to Aldehydes and Ketones Catalyzed by Rhodium(I) Complexes in Basic, Aqueous Solutions
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| Id. |
8171148 |
| Idioma |
inglés
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| Titulo |
Inter- and Intramolecular Additions of 1-Alkenylboronic Acids or Esters to Aldehydes and Ketones Catalyzed by Rhodium(I) Complexes in Basic, Aqueous Solutions |
| Autor(es) |
Takezawa, Akinori
Yamaguchi, Kenji
Ohmura, Toshimichi
Yamamoto, Yasunori
Miyaura, Norio
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| Location |
http://hdl.handle.net/2115/14622
Synlett. 10, 2002, 1733-1735
http://dx.doi.org/10.1055/s-2002-34219
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| Versión |
1.0 |
| Estado |
Final
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| Descripción |
Grignard-type addition reaction of 1-alkenylboronic acids or their esters to aldehydes or ketones were carried out in aqueous MeOH or DME in the presence of KOH (1 equivalent) and an RhCl(dppf) or Rh(OH)(dppf) catalyst (3 mol%). The utility of the protocol was demonstrated in the corresponding intramolecular reaction giving cyclic homoallylic alcohols.
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| Tipo |
83538 bytes
application/pdf
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| Palabras clave |
alkenylboron
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| Tipo de recurso |
article (author version)
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| Tipo de Interactividad |
Expositivo
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| Nivel de Interactividad |
muy bajo
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| Audiencia |
Estudiante
Profesor
Autor
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| Estructura |
Atomic |
| Coste |
no
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| Copyright |
sí
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| Formatos |
83538 bytes
application/pdf
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| Requerimientos técnicos |
Browser: Any
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| Fecha de contribución |
26-oct-2007 |
| Contacto |
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