Resource data
Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones
Yamamoto, Yasunori
Fujita, Masayoshi
Miyaura, Norio
Location:
http://hdl.handle.net/2115/14625
Synlett. 2000(5), 2002, 767-768
The rhodium-catalyzed conjugate addition of (E)-Me3SiCH2CH=CHB(OiPr)2 or (Z)-Me3SiCH2(C4H9)C=CHB(OiPr)2 to enones provided a novel method for the synthesis of allylsilicone compounds possessing a carbonyl group in the same molecule, which are versatile intermediates for intramolecular allylsilylation, giving cyclobutanols on treatment with Bu4NF.
Belongs to: Hokkaido University Collection of Scholarly and Academic Papers
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Detalles del recurso
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Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones
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| Id. |
8171151 |
| Idioma |
inglés
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| Titulo |
Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones |
| Autor(es) |
Yamamoto, Yasunori
Fujita, Masayoshi
Miyaura, Norio
|
| Location |
http://hdl.handle.net/2115/14625
Synlett. 2000(5), 2002, 767-768
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| Versión |
1.0 |
| Estado |
Final
|
| Descripción |
The rhodium-catalyzed conjugate addition of (E)-Me3SiCH2CH=CHB(OiPr)2 or (Z)-Me3SiCH2(C4H9)C=CHB(OiPr)2 to enones provided a novel method for the synthesis of allylsilicone compounds possessing a carbonyl group in the same molecule, which are versatile intermediates for intramolecular allylsilylation, giving cyclobutanols on treatment with Bu4NF.
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| Tipo |
92777 bytes
application/pdf
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| Palabras clave |
allylsilicone
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| Tipo de recurso |
article (author version)
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| Tipo de Interactividad |
Expositivo
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| Nivel de Interactividad |
muy bajo
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| Audiencia |
Estudiante
Profesor
Autor
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| Estructura |
Atomic |
| Coste |
no
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| Copyright |
sí
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| Formatos |
92777 bytes
application/pdf
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| Requerimientos técnicos |
Browser: Any
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| Fecha de contribución |
26-oct-2007 |
| Contacto |
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