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Descripción

The gas-phase carbonyl products of α-pinene, β-pinene, and d-limonene have been identified and their concentrations measured in experiments involving sunlight irradiations of mixtures of terpene (1-2 ppm) and NO (0.25 ppm) in air. In turn, sunlight irradiations of carbonyl-NO_x mixtures have been carried out for the major high molecular weight carbonyl products of β-pinene (6,6-dimethylbicyclo[3.1.1] heptan-2-one) and d-limonene (4-acetyl-1-methylcyclohexene), and the corresponding carbonyl products have been identified. The nature and yields of these carbonyl products are discussed in terms of oxidation mechanisms involving the OH-terpene, ozone-terpene, OH-carbonyl, and ozone-carbonyl reactions.

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Caltech Authors  

Autor(es)

Grosjean, Daniel -  Williams, Edwin L., II -  Seinfeld, John H. - 

Id.: 71311626

Versión: 1.0

Estado: Final

Tipo de recurso: Article  -  PeerReviewed  - 

Tipo de Interactividad: Expositivo

Nivel de Interactividad: muy bajo

Audiencia: Estudiante  -  Profesor  -  Autor  - 

Estructura: Atomic

Coste: no

Copyright: sí

Requerimientos técnicos:  Browser: Any - 

Relación: [References] http://resolver.caltech.edu/CaltechAUTHORS:20180510-152205768
[References] https://authors.library.caltech.edu/86354/

Fecha de contribución: 15-may-2018

Contacto:

Localización:
* Grosjean, Daniel and Williams, Edwin L., II and Seinfeld, John H. (1992) Atmospheric oxidation of selected terpenes and related carbonyls: gas-phase carbonyl products. Environmental Science and Technology, 26 (8). pp. 1526-1533. ISSN 0013-936X. http://resolver.caltech.edu/CaltechAUTHORS:20180510-152205768

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