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An organically modified silicate (ormosil) as a matrix for the fabrication of dissolved oxygen-sensing film was produced. The process included taking tetramethoxysilane (TMOS) and dimethyldimethoxysilane (DiMe-DMOS) as precursor and running a reaction at 60 degreesC in an open vial, which accelerates hydrolysis and condensation and results in the formation of emulsion. The film doped with tris-(4,7-diphenyl-1,10-phenanthroline) ruthenium(H) ([Ru(dpp)(3)](2+)) as an oxygen indicator exhibited a good linear relationship, fast response time, long-term stability and enhanced sensitivity to dissolved oxygen after optimizing the sol-gel processing parameters. The properties and the oxygen-sensing behavior of the film were investigated. The results presented here emphasized the significance of ormosil as a matrix for dissolved oxygen-sensing. (C) 2002 Elsevier Science B.V. All rights reserved.

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DSpace at Xiamen University Library  


Chen, X -  Zhong, ZM -  Li, Z -  Jiang, YQ -  Wang, XR -  王小如 -  Wong, KY - 

Id.: 55259650

Idioma: inglés  - 

Versión: 1.0

Estado: Final

Palabras claveormosil - 

Tipo de recurso: Article  - 

Tipo de Interactividad: Expositivo

Nivel de Interactividad: muy bajo

Audiencia: Estudiante  -  Profesor  -  Autor  - 

Estructura: Atomic

Coste: no

Copyright: sí

Requerimientos técnicos:  Browser: Any - 

Fecha de contribución: 06-may-2012


* 0925-4005

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