1) La descarga del recurso depende de la página de origen
2) Para poder descargar el recurso, es necesario ser usuario registrado en Universia


Opción 1: Descargar recurso

Opción 2: Descargar recurso

Detalles del recurso

Descripción

The first section of this dissertation introduces the basic concepts that are necessary for the quantitative description of electrode kinetics. The refinements and corrections in the rate equation that are due to a detailed model of the electrical double layer, and to the potential step relaxation technique are introduced and discussed.

A discussion of the non-linear statistical analysis techniques that are necessary for a rigorous analysis of rate equation is presented in the second section. The estimates of the precision of the desired parameters obtained by using statistical methods can be used as a measure of the efficiency of an experiment. Their use as measures of "kinetic information density" is developed and illustrated by comparing charge and current measurement in the potential step technique. Previous approaches to the subject of "kinetic information density" are discussed and compared to the results from statistical analysis.

The third section describes the computerized data acquisition and analysis system that was designed and used for the study of electrode kinetics.

The final section presents the results of the kinetic studies undertaken on the Zn+2/Zn(Hg) system in 1 F NaNO3, 1 F NaClO4, and 1 F NaCl supporting electrolytes. Ensemble averaging is used in these studies to increase precision and its values is illustrated.

The results that are obtained for the rate constants in the various supporting electrolytes are compared and it is shown that the rates are comparable in NaNO3 and NaClO4 supporting electrolytes but significantly greater in 1 F NaCl. These results are compared with results of previous investigators and the quality of the results of this thesis are compared to those of previous investigators.


Pertenece a

CaltechTHESIS  

Autor(es)

Abel, Roger Henry - 

Id.: 71078754

Versión: 1.0

Estado: Final

Tipo:  application/pdf - 

Tipo de recurso: Thesis  -  NonPeerReviewed  - 

Tipo de Interactividad: Expositivo

Nivel de Interactividad: muy bajo

Audiencia: Estudiante  -  Profesor  -  Autor  - 

Estructura: Atomic

Coste: no

Copyright: sí

Formatos:  application/pdf - 

Requerimientos técnicos:  Browser: Any - 

Relación: [References] http://resolver.caltech.edu/CaltechTHESIS:03092018-170506721
[References] https://thesis.library.caltech.edu/10768/

Fecha de contribución: 08-may-2018

Contacto:

Localización:

Otros recursos que te pueden interesar

  1. Authoritarian Governments and the Corrosion of the Social Protection Network in Brazil Abstract What are the impacts of the austerity reforms on the social protection network and the lega...
  2. State, Economy and Democracy in Brazil and Latin America
  3. Sensitivity analysis of a member under compression via Monte Carlo method The present work studies the application of a probabilistic methodology in the sensitivity analysis ...
  4. Can resources act as capabilities foundations? A bibliometric analysis The objective of this article is to record the trends of study regarding the relationships between r...
  5. Les grandes dates de la Ve République Utilísima publicación en que se resumen los acontecimientos políticos más significativos de la Vª Re...

Otros recursos de la mismacolección

  1. Two Topics in Particle Physics. I. Tests for Helicity Conservation and Spin-Parity Selection Rules in Diffraction Dissociation. II. Independent Production of Pions

    I. Tests for Helicity Conservation and Spin-Parity Selection Rules in Diffraction Dissociation

  2. I. Studies in Isomerism: Permutations, Point Group Symmetries, and Isomer Counting. II. Studies in the Photochemistry of Coumarin and Certain Coumarin Derivatives

    PART I

    Polya's group theoretical method for calculating the permutation isomers of...

  3. Investigations on Lateralization of Function in the Disconnected Hemispheres of Man

    The effect of long standing cerebral damage upon the pattern of functional lateralization reveale...

  4. Conformational Study of Some Fluorine-Labeled Cyclic Compounds by Nuclear Magnetic Resonance Spectroscopy. I. 1,1-Difluorocyclodecane and 3,3-Difluoro-trans-Cyclodecene. II. γ,γ-Difluoro-ε-Caprolactone and γ,γ-Difluoro-ε-Caprolactam.

    Low-temperature fluorine magnetic resonance spectroscopy has been used to investigate the conform...

  5. Magnetic States in Amorphous Pd_(41)Ni_(41)B_(18) Alloys Containing Chromium and Iron

    Amorphous alloys Pd41Ni41B18 containing up to 4 at.% of Cr or Fe...

Aviso de cookies: Usamos cookies propias y de terceros para mejorar nuestros servicios, para análisis estadístico y para mostrarle publicidad. Si continua navegando consideramos que acepta su uso en los términos establecidos en la Política de cookies.