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Sidewall oxidation and complexation of carbon nanotubes by base-catalyzed cycloaddition of transition metal oxide: A theoretical prediction

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Pertenece a: DSpace at Xiamen University Library  

Descripción: By means of a two-layered ONIOM (B3LYP/LANL2DZ:UFF) approach, we predicted the viable oxidation of the sidewalls of single-wall carbon nanotubes by transition metal oxide (OsO4), which gives rise to osmate ester adducts on the nanotube sidewall. We believe that the as-formed osmate ester adducts can be a good starting point for further functionalization, hence, introducing high flexibility to carbon nanotubes for further manipulations for various potential applications.

Autor(es): Lu, X -  吕鑫 -  Tian, F -  Feng, YB -  Xu, X -  徐昕 -  Wang, NQ -  Zhang, QN -  张乾二 - 

Id.: 55259651

Idioma: inglés  - 

Versión: 1.0

Estado: Final

Tipo de recurso: Article  - 

Tipo de Interactividad: Expositivo

Nivel de Interactividad: muy bajo

Audiencia: Estudiante  -  Profesor  -  Autor  - 

Estructura: Atomic

Coste: no

Copyright: sí

Requerimientos técnicos:  Browser: Any - 

Fecha de contribución: 06-may-2012

Contacto:

Localización:
* Nano Letters, 2002, 2 (11):1325–1327
* 1530-6984


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