Detalles del recurso


The terminal carbido ligand of (Pcy_3)_2(Cl)_2RuC coordinates to other metal centers in a σ-donor fashion, as in (Pcy_3)_2(Cl)_2Ru≡C–Pd(Cl)_2(Sme_2) and (Pcy_3)_2(Cl)_2Ru≡C–Mo(CO)_5.

Pertenece a

Caltech Authors  


Hejl, Andrew -  Trnka, Tina M. -  Day, Michael W. -  Grubbs, Robert H. - 

Id.: 54729163

Versión: 1.0

Estado: Final

Tipo:  application/pdf -  application/msword -  text/plain -  image/png - 

Tipo de recurso: Article  -  PeerReviewed  - 

Tipo de Interactividad: Expositivo

Nivel de Interactividad: muy bajo

Audiencia: Estudiante  -  Profesor  -  Autor  - 

Estructura: Atomic

Coste: no

Copyright: sí

Formatos:  application/pdf -  application/msword -  text/plain -  image/png - 

Requerimientos técnicos:  Browser: Any - 

Relación: [References]

Fecha de contribución: 27-dic-2012


* Hejl, Andrew and Trnka, Tina M. and Day, Michael W. and Grubbs, Robert H. (2002) Terminal ruthenium carbido complexes as σ-donor ligands. Chemical Communications, 2002 (21). pp. 2524-2525. ISSN 1359-7345

Otros recursos del mismo autor(es)

  1. Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation A new strategy for the functionalization of sterically hindered terminal olefins is reported. Alkene...
  2. Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (−)-Aspewentin A, B, and C The direct α-vinylation of carbonyl compounds that forms a quaternary stereocenter is a challenging ...
  3. (Dicyclohexylphosphino)borane, BH_3PH(C_6H_(11))_2, a Precursor to Water-Soluble Phosphine Ligands (Dicyclohexylphosphino) borane is a precursor in the synthesis of water-soluble phosphines. The bora...
  4. Potassium tert-Butoxide-Catalyzed Dehydrogenative Cross-Coupling of Heteroarenes with Hydrosilanes A. 1-Methyl-2-(triethylsilyl)-1H-indole (2). An oven-dried 100-mL round-bottom Schlenk flask is equi...
  5. A Diphenylcyclopropene Complex of Tungsten, [WCl_2O(PMePh_2)_2(η^2-3,3-diphenylcyclopropene)], Precursor to a Tungsten–Oxo–Olefin Metathesis Catalyst The title compound, dichlorobis(methyldiphenylphosphine-P) [(1,2-[η])-3,3-diphenylcyclopropene]oxotu...

Otros recursos de la misma colección

  1. Starvation and recovery in the deep-sea methanotroph Methyloprofundus sedimenti In the deep ocean, the conversion of methane into derived carbon and energy drives the establishment...
  2. Homogenization and Path Independence of the J-Integral in Heterogeneous Materials The J-integral that determines the driving force on a crack tip is a central concept of fracture mec...
  3. Unstable neurons underlie a stable learned behavior Motor skills can be maintained for decades, but the biological basis of this memory persistence rema...
  4. SOXE neofunctionalization and elaboration of the neural crest during chordate evolution During chordate evolution, two genome-wide duplications facilitated acquisition of vertebrate traits...
  5. Microresonator soliton dual-comb spectroscopy Rapid characterization of optical and vibrational spectra with high resolution can identify species ...

Aviso de cookies: Usamos cookies propias y de terceros para mejorar nuestros servicios, para análisis estadístico y para mostrarle publicidad. Si continua navegando consideramos que acepta su uso en los términos establecidos en la Política de cookies.